KNa2La2(BO3)3: a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO3] triangles and distorted [LaO9] polyhedra-Reference-Cited by-同舟云学术

KNa₂La₂(BO₃)₃: a shortite-type lanthanide borate exhibiting strong nonlinear optical activity induced by isolated [BO₃] triangles and distorted [LaO₉] polyhedra

Published:2023 Issue:18 Volume:10 Page:5488-5495
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Song Jie¹,Li Conggang¹^ORCID,Jiao Jinmiao¹,She Yuheng¹,Zhao Wenli¹,Liang Fei²^ORCID,Ye Ning¹,Hu Zhanggui¹,Wu Yicheng¹

Affiliation:

1. Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, Tianjin University of Technology, Tianjin 300384, China

2. State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, China

Abstract

A new rare earth borate KNa2La2(BO3)3 was experimentally fabricated. It fully achieved the coexistence of strong phase-matching SHG response (2.6 × KDP), a short UV cut-off edge (212 nm) and a wide band gap (5.3 eV).

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI01004J

Reference50 articles.

1. Nonlinear Optical Materials

2. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures