Entropy-stabilized metal oxide nanoparticles supported on reduced graphene oxide as a highly active heterogeneous catalyst for selective and solvent-free oxidation of toluene: a combined experimental and numerical investigation

Author:

Mehrabi-Kalajahi Seyedsaeed12ORCID,Moghaddam Ahmad Ostovari3,Hadavimoghaddam Fahimeh4,Varfolomeev Mikhail A.12ORCID,Zinnatullin Almaz L.5ORCID,Vakhitov Iskander5ORCID,Minnebaev Kamil R.6ORCID,Emelianov Dmitrii A.2,Uchaev Daniil3,Cabot Andreu78ORCID,Il'yasov Il'dar R.2,Davletshin Rustam R.9,Trofimov Evgeny3,Khasanova Nailia M.6ORCID,Vagizov Farit G.5

Affiliation:

1. Department of Petroleum Engineering, Kazan Federal University, Kazan 420008, Russia

2. Department of Physical Chemistry, Kazan Federal University, Kazan 420008, Russia

3. Department of Materials Science, Physical and Chemical Properties of Materials, South Ural State University, 76 Lenin Ave, Chelyabinsk, 454080, Russia

4. Institute of Unconventional Oil & Gas, Northeast Petroleum University, Heilongjiang, Daqing, 163318, China

5. Institute of Physics, Kazan Federal University, Kazan 420008, Russia

6. Institute of Geology and Petroleum Technologies, Kazan Federal University, Kazan, 420008, Russia

7. Catalonia Institute for Energy Research – IREC, 08930 Sant Adrià de Besòs, Spain

8. ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

9. Department of Organic Chemistry, Kazan Federal University, Kazan 420008, Russia

Abstract

Noble metal-free heterogeneous catalysts are highly desired for selective and solvent-free oxidation reactions. However, their practical application has been greatly restricted by their moderate activity.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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