An umpolung strategy for rapid access to thermally activated delayed fluorescence (TADF) materials based on phenazine-Reference-Cited by-同舟云学术

An umpolung strategy for rapid access to thermally activated delayed fluorescence (TADF) materials based on phenazine

Published:2022 Issue:10 Volume:58 Page:1581-1584
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Huaxing¹,Guo Qiang²,Cheng Hu¹,Ran Chunhao¹,Wu Di¹^ORCID,Lan Jingbo¹^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China

2. College of Optoelectronic Engineering, Chengdu University of Information Technology, 24 Xuefu Road, Chengdu 610225, P. R. China

Abstract

Ag(I)-promoted regioselective intramolecular radical nucleophilic addition/rearrangement of 2-aryl diazaboroles has been accomplished to construct phenazine structures, which is an umpolung strategy based on the classical electrophilic mechanism.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC06705B

Reference41 articles.

1. Phenazine Natural Products: Biosynthesis, Synthetic Analogues, and Biological Activity

2. Recent developments in the isolation, biological function, biosynthesis, and synthesis of phenazine natural products

3. Recent Progress of Highly Efficient Red and Near-Infrared Thermally Activated Delayed Fluorescent Emitters

4. Purely Organic Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes

5. Red/Near‐Infrared Thermally Activated Delayed Fluorescence OLEDs with Near 100 % Internal Quantum Efficiency

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