Reversibility limitations of metal exsolution reactions in niobium and nickel co-doped strontium titanate

Author:

Weber Moritz L.123ORCID,Sohn Yoo Jung3ORCID,Dittmann Regina2ORCID,Waser Rainer24ORCID,Menzler Norbert H.35ORCID,Guillon Olivier35ORCID,Lenser Christian3ORCID,Nems̆ák Slavomír16ORCID,Gunkel Felix2ORCID

Affiliation:

1. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

2. Peter Gruenberg Institute (PGI-7) and JARA-FIT, Forschungszentrum Juelich GmbH, Wilhelm-Johnen-Straße, 52425 Juelich, Germany

3. Institute of Energy and Climate Research (IEK-1), Forschungszentrum Juelich GmbH, Wilhelm-Johnen-Straße, 52425 Juelich, Germany

4. Institute for Electronic Materials (IWE 2), RWTH Aachen University, Sommerfeldstraße 18/24, 52074 Aachen, Germany

5. Institute of Mineral Engineering (GHI), RWTH Aachen University, Forckenbeckstraße 33, 52074, Aachen, Germany

6. Department of Physics, University of California, Davis, California 95616, USA

Abstract

Reversible metal exsolution and re-dissolution of metal cations in perovskite host lattices hold the potential for the development of regenerable metal-oxide catalysts. However, the reversibility of metal exsolution reactions is often limited.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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