Aqueous chemistry of Ce(iv): estimations using actinide analogues

Author:

Marsac Rémi12345ORCID,Réal Florent63789,Banik Nidhu Lal1011121314,Pédrot Mathieu12345,Pourret Olivier1516179ORCID,Vallet Valérie63789ORCID

Affiliation:

1. Géosciences Rennes UMR 6118

2. Université Rennes 1

3. CNRS

4. 35042

5. Rennes Cedex

6. Univ. Lille

7. UMR 8523 – PhLAM – Physique des Lasers Atomes et Molécules

8. F-59000 Lille

9. France

10. JRC-KARLSRUHE

11. G.II.6 – Nuclear Safeguards and Forensics

12. European Commission

13. D-76125 Karlsruhe

14. Germany

15. HydrISE

16. UniLaSalle

17. 60026 Beauvais Cedex

Abstract

Quantum chemical calculations and a comparison of cerium(iv)/actinide(iv) justify the estimation of cerium(iv) aqueous speciation using plutonium(iv) as an analogue.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference77 articles.

1. An electrostatic approach for the prediction of actinide complexation constants with inorganic ligands-application to carbonate complexes

2. R. Guillaumont , T.Fanghänel, J.Fuger, I.Grenthe, V.Neck, D. A.Palmer and M. H.Rand, Chemical Thermodynamics, Vol. 5, Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, OECD Nuclear Energy Agency, Data Bank, Elsevier, Amsterdam, 2003

3. Actinide speciation in the environment

4. Colloid-borne forms of tetravalent actinides: A brief review

5. Neptunium and Plutonium Solubilities in a Yucca Mountain Groundwater

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