Synthesis of nickel and palladium complexes with diarylamido-based unsymmetrical pincer ligands and application for norbornene polymerization-Reference-Cited by-同舟云学术

Synthesis of nickel and palladium complexes with diarylamido-based unsymmetrical pincer ligands and application for norbornene polymerization

Published:2019 Issue:2 Volume:48 Page:609-617
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Hui¹²³⁴⁵,Yuan Haibin¹²³⁴⁵,Shi Xiaochao¹²³⁴⁵^ORCID

Affiliation:

1. Department of Polymer Materials

2. College of Materials Science and Engineering

3. Shanghai University

4. Shanghai 200444

5. China

Abstract

Nickel and palladium complexes chelating diarylamido-based unsymmetrical [PNN^ox] pincer ligands have been synthesized and used as catalysts for norbornene polymerization with activities up to 40.3 × 10⁵ g of PNB (mol of Pd)⁻¹ h⁻¹ upon the activation of methylaluminoxane (MAO).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04413A

Reference83 articles.

1. Advances in Non-Metallocene Olefin Polymerization Catalysis

2. Ethylene oligomerization, homopolymerization and copolymerization by iron and cobalt catalysts with 2,6-(bis-organylimino)pyridyl ligands

3. Metallocene and related catalysts for olefin, alkyne and silane dimerization and oligomerization