Unimolecular decomposition of acetyl peroxy radical: a potential source of tropospheric ketene
Author:
Affiliation:
1. CSIR – National Institute of Science
2. Technology and Development Studies
3. New Delhi-110012
4. India
5. Department of Physics
6. Bharathiar University
7. Coimbatore – 641 046
Abstract
The unimolecular dissociation of acetyl peroxy radical leads to ketene and HO2 in the troposphere via a red-light driven process.
Funder
Department of Science and Technology, Ministry of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP04590J
Reference46 articles.
1. Laboratory studies of organic peroxy radical chemistry: an overview with emphasis on recent issues of atmospheric significance
2. Mechanism and Kinetics of the Atmospheric Oxidative Degradation of Dimethylphenol Isomers Initiated by OH Radical
3. Investigation of the radical product channel of the CH3C(O)O2 + HO2 reaction in the gas phase
4. Direct detection of OH formation in the reactions of HO<sub>2</sub> with CH<sub>3</sub>C(O)O<sub>2</sub> and other substituted peroxy radicals
5. Unimolecular Reactions of Peroxy Radicals in Atmospheric Chemistry and Combustion
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