Enantioselective access to spiro[2,3-dihydrofuran-2,2′-inden-1-ones]<i>via</i>zinc catalyzed [3 + 2] annulation of α-hydroxy-1-indanones with yne

Enantioselective access to spiro[2,3-dihydrofuran-2,2′-inden-1-ones]viazinc catalyzed [3 + 2] annulation of α-hydroxy-1-indanones with yne–enones

Published:2023 Issue:16 Volume:10 Page:4061-4067
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Han Jiao-Jiao¹,Jiang Tao¹,Zhang Cui¹,Cui Dan-Dan¹,Hua Yuan-Zhao¹^ORCID,Mei Guang-Jian¹^ORCID,Wang Min-Can¹^ORCID,Jia Shi-Kun¹^ORCID

Affiliation:

1. College of Chemistry and Institute of Green Catalysis, Zhengzhou University, Zhengzhou City, Henan 450000, P. R. China

Abstract

An enantioselective construction of spiro[1-indanone-dihydrofurans] has been accomplished through zinc-catalyzed [3 + 2] annulationviaa Brønsted base and Lewis acid cooperative activation model.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Natural Science Foundation of Henan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00825H

Reference62 articles.

1. New development in the enantioselective synthesis of spiro compounds

2. Enantioselective methodologies for the synthesis of spiro compounds

3. Catalytic asymmetric synthesis of spirooxindoles: recent developments

4. Annulations involving 1-indanones to access fused- and spiro frameworks

5. Recent progress in the synthesis of the furanosteroid family of natural products

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