Organophosphate-catalyzed bulk ring-opening polymerization as an environmentally benign route leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane-Reference-Cited by-同舟云学术

Organophosphate-catalyzed bulk ring-opening polymerization as an environmentally benign route leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane

Published:2015 Issue:24 Volume:6 Page:4374-4384
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Saito Tatsuya¹²³⁴,Aizawa Yusuke¹²³⁴,Tajima Kenji⁵⁶²⁷⁴,Isono Takuya⁵⁶²⁷⁴,Satoh Toshifumi⁵⁶²⁷⁴

Affiliation:

1. Graduate School of Chemical Sciences and Engineering

2. Hokkaido University

3. Sapporo, 060-8628

4. Japan

5. Division of Biotechnology and Macromolecular Chemistry

6. Faculty of Engineering

7. Sapporo 060-8628

Abstract

To expand the potential of an organophosphate catalyst, ring-opening polymerization of cyclic esters, cyclic ester-ether, and cyclic carbonate was demonstrated under bulk conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2015/PY/C5PY00533G

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3. Kinetics and Mechanism of Cyclic Esters Polymerization Initiated with Tin(II) Octoate. 3. Polymerization of l,l-Dilactide

4. Poly(lactones). 9. Polymerization mechanism of metal alkoxide initiated polymerizations of lactide and various lactones

5. Living polymerization and selective end functionalization of iε-caprolactone using zinc alkoxides as initiators

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