Chemoselective one-pot cleavage and oxidation of silyl ethers to corresponding carbonyl compounds using IBX and acid catalysts
Author:
Affiliation:
1. Department of Synthetic Medicinal Chemistry, Faculty of Pharmaceutical Sciences, Hoshi University, 2-4-41 Ebara, Shinagawa-ku, Tokyo 142-8501, Japan
Abstract
Funder
Japan Society for the Promotion of Science
Hoshi University
Publisher
Royal Society of Chemistry (RSC)
Link
http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00858H
Reference29 articles.
1. P. G. M.Wuts , Protective Groups in Organic Synthesis , Wiley-Interscience , New Jersey , 5th edn, 2014
2. Selective deprotection of silyl ethers
3. Silyl Ethers as Protective Groups for Alcohols: Oxidative Deprotection and Stability under Alcohol Oxidation Conditions
4. Mild and Efficient Method for Oxidative Deprotection of Trimethylsilyl Ethers Mediated by Tetraethylammonium Superoxide
5. Oxidative deprotection of trimethylsilyl ethers under solvent-free conditions using K2S2O8 in the presence of catalytic amount of [bmim]Br
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