Field induced single ion magnet behavior in Co<sup>II</sup> complexes in a distorted square pyramidal geometry-Reference-Cited by-同舟云学术

Field induced single ion magnet behavior in Co^II complexes in a distorted square pyramidal geometry

Published:2023 Issue:41 Volume:52 Page:14807-14821
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dey Atanu¹²^ORCID,Ali Junaid²,Moorthy Shruti³^ORCID,Gonzalez Jessica Flores⁴,Pointillart Fabrice⁴^ORCID,Singh Saurabh Kumar³^ORCID,Chandrasekhar Vadapalli²⁵^ORCID

Affiliation:

1. Department of Chemistry, Gandhi Institute of Technology and Management (GITAM), NH 207, Nagadenehalli, Doddaballapur Taluk, Bengaluru 561203, India

2. Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad, 500 046, India

3. Department of Chemistry, Indian Institute of Technology Hyderabad, Kandi, Sangareddy, 502285, Telangana, India

4. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, 35000 Rennes, France

5. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India

Abstract

We report three CoII-based square pyramidal complexes, [CoII(L)(X)2] (X = SeCN, Cl and Br). The structural distortions in these complexes induce a variation in the anisotropy parameter D and hence in their magnetic properties.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Gandhi Institute of Technology and Management

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01769A

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