PDI–trityl dyads as photogenerated molecular spin qubit candidates

Author:

Mayländer Maximilian1ORCID,Kopp Kevin2,Nolden Oliver3,Franz Michael1ORCID,Thielert Philipp1ORCID,Vargas Jentzsch Andreas4ORCID,Gilch Peter3ORCID,Schiemann Olav2ORCID,Richert Sabine1ORCID

Affiliation:

1. Institute of Physical Chemistry, University of Freiburg, Albertstraße 21, 79104 Freiburg, Germany

2. Clausius Institute of Physical and Theoretical Chemistry, University of Bonn, Wegelerstraße 12, 53115 Bonn, Germany

3. Institute of Physical Chemistry, Heinrich Heine University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany

4. SAMS Research Group, Université de Strasbourg, CNRS, Institut Charles Sadron UPR 22, 67000 Strasbourg, France

Abstract

Quartet states, generated after photoexcitation of chromophore–radical dyads, are promising for applications in quantum sensing. We demonstrate the potential of trityl radicals for improving their coherence properties and spectral addressability.

Funder

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Ministerium für Kultur und Wissenschaft des Landes Nordrhein-Westfalen

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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