Redox-site accessibility of composites containing a 2D redox-active covalent organic framework: from optimization to application

Author:

Günther Tyran1,Oka Kouki2ORCID,Olsson Sandra1ORCID,Åhlén Michelle1,Tohnai Norimitsu2,Emanuelsson Rikard3ORCID

Affiliation:

1. Nanotechnology and Functional Materials, Department of Materials Science and Engineering, The Ångström Laboratory, Uppsala University, Box 35, SE-751 03 Uppsala, Sweden

2. Center for Future Innovation (CFi) and Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

3. Department of Chemistry – BMC, Uppsala University, Box 576, SE-751 23 Uppsala, Sweden

Abstract

A systematic method is presented which demonstrates how accessing more redox-active sites in a poorly conducting 2D COF can be done in a rational manner. An optimised and dramatically improved charge-storage composite was produced using this method.

Funder

Shorai Foundation for Science and Technology

Stiftelsen Åforsk

Nipponham Foundation

Svenska Forskningsrådet Formas

Magnus Bergvalls Stiftelse

Stiftelsen Lars Hiertas Minne

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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