Reactivity of a quasi-four-coordinate butylmagnesium cation-Reference-Cited by-同舟云学术

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Reactivity of a quasi-four-coordinate butylmagnesium cation

Published:2023 Issue:6 Volume:52 Page:1533-1537
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ankur ¹^ORCID,Sharma Deepti¹^ORCID,Andrews Alex P.¹,Venugopal Ajay¹^ORCID

Affiliation:

1. School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Vithura, Thiruvananthapuram 695551, India

Abstract

We present the first straightforward synthesis of a cationic magnesium hydride from an alkyl magnesium cation using pinacolborane/phenyl silane.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00018D

Reference43 articles.

1. Alkaline earths as main group reagents in molecular catalysis

2. S.Harder , Early Main Group Metal Catalysis: Concepts and Reactions , Wiley–VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2020 , p. 1

3. Recent Developments in Homogeneous Organomagnesium Catalysis

4. Ankur , S.Kundu , S.Banerjee and A.Venugopal , Magnesium Complexes in Organic Synthesis , in Comprehensive Organometallic Chemistry IV , ed. G. Parkin , K. Meyer and D. O'hare , Elsevier , 2022 , p. 78

5. Z.Rappoport and I.Marek , The Chemistry of Organomagnesium Compounds , John Wiley & Sons, Ltd , Chichester , 2008

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