Antiferromagnetic quaternary chalco-halide Ba3(FeS4)I with long Fe⋯Fe distances

Author:

Xiao Yi12,Zhang Xian2ORCID,Wang Ruiqi1,An Simin3ORCID,Huang Fuqiang14

Affiliation:

1. Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, 202 Chengfu Road, Beijing, 100871, P. R. China

2. Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology, Beijing, 100094, P. R. China

3. Laboratory of Computational Physics, Institute of Applied Physics and Computational Mathematics, Beijing, 100088, P. R. China

4. Department CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai, 200050, P. R. China

Abstract

A new chalco-halide Ba3(FeS4)I was synthesized, which shows a remarkable antiferromagnetic phase transition at 108 K realized by the novel Fe–S⋯S–Fe super–super exchanges.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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