Asymmetric aza-Henry reaction to provide oxindoles with quaternary carbon stereocenter catalyzed by a metal-templated chiral Brønsted base-Reference-Cited by-同舟云学术

Asymmetric aza-Henry reaction to provide oxindoles with quaternary carbon stereocenter catalyzed by a metal-templated chiral Brønsted base

Published:2015 Issue:8 Volume:2 Page:968-972
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Hu Ying¹²³⁴⁵,Zhou Zijun¹²³⁴⁵,Gong Lei¹²³⁴⁵,Meggers Eric¹²³⁴⁵

Affiliation:

1. Key Laboratory for Chemical Biology of Fujian Province and Department of Chemical Biology

2. College of Chemistry and Chemical Engineering

3. Xiamen University

4. Xiamen 361005

5. People's Republic of China

Abstract

An inert octahedral chiral-at-metal iridium(iii) complex serves as a highly effective chiral Brønsted base catalyst for implementing a quaternary carbon stereocenter.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00132C

Reference82 articles.

1. Asymmetric Catalytic Aza-Henry Reactions Leading to 1,2-Diamines and 1,2-Diaminocarboxylic Acids

2. Catalytic Enantioselective Aza‐Henry Reactions

3. Nitro-Mannich Reaction

4. Enantioselective Aza-Henry Reaction Catalyzed by a Bifunctional Organocatalyst

5. A chiral molecular recognition approach to the formation of optically active quaternary centres in aza-Henry reactions

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