Ni-Catalysed Intramolecular [4+4]-cycloadditions of bis-dienes towards eight-membered fused bicyclic systems: a combined experimental and computational study
Author:
Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ) and
2. The Barcelona Institute of Science and Technology (BIST)
3. 43007 Tarragona
4. Spain
5. Departament de Química
6. Universitat de les Illes Balears (UIB)
7. 07122 Palma de Mallorca
8. ICREA
Abstract
Nickel(0) complexes derived from electron-rich triarylphosphines as efficient catalysts for intramolecular [4+4]-cycloadditions of an array of structurally diverse bis-dienes.
Funder
Ministerio de Economía y Competitividad
Institut Català d'Investigació Química
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00684A
Reference25 articles.
1. N. Blanchard and J.Eustache , in Metathesis in Natural Product Synthesis: Strategies, Substrates and Catalysts , ed. J. Cossy , S. Arseniyadis and C. Meyer , Wiley-VCH Verlag GmbH & Co. KGaA , 2010 , ch. 1, pp. 1–43
2. Rhodium-Catalyzed [5 + 2 + 1] Cycloaddition of Ene–Vinylcyclopropanes and CO: Reaction Design, Development, Application in Natural Product Synthesis, and Inspiration for Developing New Reactions for Synthesis of Eight-Membered Carbocycles
3. [4+ 4]-Cycloaddition Reactions in the Total Synthesis of Naturally Occurring Eight-Membered Ring Compounds
4. The [4 + 4] cycloaddition and its strategic application in natural product synthesis
5. Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Eight-Membered Carbocycles
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