The interparticle distance limit for multiple exciton dissociation in PbS quantum dot solid films

Author:

Nakazawa Naoki1234,Zhang Yaohong1234ORCID,Liu Feng1234,Ding Chao1234,Hori Kanae1234,Toyoda Taro1234,Yao Yingfang56789ORCID,Zhou Yong56789ORCID,Hayase Shuzi1011124,Wang Ruixiang13141516,Zou Zhigang56789,Shen Qing1234ORCID

Affiliation:

1. Faculty of Informatics and Engineering

2. The University of Electro-Communications

3. Tokyo 182-8585

4. Japan

5. Ecomaterials and Renewable Energy Research Center

6. Jiangsu Key Laboratory for Nano Technology

7. National Laboratory of Solid State Microstructures

8. Nanjing University

9. Nanjing 210093

10. Faculty of Life Science and Systems Engineering

11. Kyushu Institute of Technology

12. Fukuoka 808-0196

13. Beijing Engineering Research Centre of Sustainable Energy and Buildings

14. Beijing University of Civil Engineering and Architecture

15. Beijing 102616

16. China

Abstract

The charge transfer rate constant knet of single exciton, biexciton and triexciton within the QD solid film is exponentially enhanced as the interparticle distance between the QDs decreases, in which the charge transfer occurs via tunneling of charges between the neighboring QDs.

Funder

Japan Science and Technology Agency

Beijing University of Civil Engineering and Architecture

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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