Field-induced single ion magnet behaviour of discrete and one-dimensional complexes containing [bis(1-methylimidazol-2-yl)ketone]-cobalt(ii) building units

Author:

Jiménez Juan-Ramón1,Xu Buqing1,El Said Hasnaa1,Li Yanling1ORCID,von Bardeleben Jurgen2,Chamoreau Lise-Marie1,Lescouëzec Rodrigue1ORCID,Shova Sergiu3,Visinescu Diana4ORCID,Alexandru Maria-Gabriela5ORCID,Cano Joan6ORCID,Julve Miguel6ORCID

Affiliation:

1. Sorbonne Université, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, 4 place Jussieu, F-75252 Paris, France

2. Sorbonne Université, Institut des NanoSciences de Paris, UMR CNRS 7588, 4 place Jussieu, F-75252 Paris, France

3. “Petru Poni” Institute of Macromolecular Chemistry, Romanian Academy, Aleea Grigore Ghica Vodă 41-A, RO-700487 Iasi, Romania

4. Coordination and Supramolecular Chemistry Laboratory, “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, Splaiul Independentei 202, Bucharest 060021, Romania

5. Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, 011061 Bucharest, Romania

6. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València, C/Catedrático José Beltrán 2, 46990 Paterna, Valencia, Spain

Abstract

Three {CoII(Rbik)2} single-ion magnets (SIMs) based on the Mebik ligand [Mebik = bis(1-methylimidazol-2-yl)ketone] and one mixed-valence {CoIII2CoII}n chain of CoII SIMs connected by diamagnetic {CoIII2(μ-2,5-dpp)(CN)8} spacers are discussed.

Funder

Sorbonne Université

Centre National de la Recherche Scientifique

Colegiul Consultativ pentru Cercetare-Dezvoltare şi Inovare

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference51 articles.

1. Single-molecule magnets and related phenomena , ed. R. Winpenny and G. Aromí , Springer , Berlin , 2006

2. O.Kahn , Molecular magnetism , Wiley-VCH , New York , 2001

3. Spin-crossover materials: properties and applications , ed. M. A. Halcrow , Wiley , Chichester , 2013

4. Magnetic bistability in a metal-ion cluster

5. Design of single chain magnets through cyanide-bearing six-coordinate complexes

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