The effect of the metal fragment on the aromaticity and synchronicity of the gold(i)-catalysed divinylcyclopropane–cycloheptadiene rearrangement

Author:

Sosa Carrizo E. Daiann12345,Fernández Israel12345

Affiliation:

1. Departamento de Química Orgánica I

2. Facultad de Ciencias Químicas

3. Universidad Complutense

4. 28040 Madrid

5. Spain

Abstract

The gold(i)-catalysed divinylcyclopropane–cycloheptadiene rearrangement has been studied computationally within the Density Functional Theory framework.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference64 articles.

1. P. J. Garratt , Aromaticity, Wiley, New York, 3rd edn, 1986

2. V. I. Minkin , M. N.Glukhovtsev and B. Y.Simkin, Aromaticity and Antiaromaticity: Electronic and Structural Aspects, Wiley, New York, 1994

3. for recent reviews about aromaticity see the special issue entitled: Aromaticity, ed. Virgil Percec, Chem. Rev., 2001, 101

4. Delocalization—pi and sigma, ed. J. A. Gladysz, Chem. Rev., 2005, 105

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