Metal ion complexes of nucleoside phosphorothioates reflecting the ambivalent properties of lead(ii)-Reference-Cited by-同舟云学术

Metal ion complexes of nucleoside phosphorothioates reflecting the ambivalent properties of lead(ii)

Published:2018 Issue:10 Volume:42 Page:7551-7559
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sigel Astrid¹²³⁴⁵,Operschall Bert P.¹²³⁴⁵,Sigel Roland K. O.¹⁶⁷⁵,Sigel Helmut¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Inorganic Chemistry

3. University of Basel

4. CH-4056 Basel

5. Switzerland

6. University of Zürich

7. CH-8057 Zürich

Abstract

The lead(ii)-lone pair leads to ambivalency: hemidirected (distorted, non-spherical) coordination spheres result from electronegative O-coordination and holodirected (symmetric, spherical) ones from less electronegative S-coordination.

Funder

Universität Basel

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Universität Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04989G

Reference93 articles.

1. R. A. Goyer , in Handbook on Toxicity of Inorganic Compounds , ed. H. G.Seiler , H.Sigel and A.Sigel , Dekker , New York , 1988 , pp. 359–382

2. Concepts on Metal Ion Toxicity , ed. H. Sigel and A. Sigel , Metal Ions in Biological Systems, Dekker , New York , 1986 , vol. 20, pp. 1–386

3. J. Molin Christensen and J.Kristiansen , in Handbook on Metals in Clinical and Analytical Chemistry , ed. H. G.Seiler , A.Sigel and H.Sigel , Dekker , New York , 1994 , pp. 425–440

4. S. Caito , A. C. B.Almeida Lopes , M. M. B.Paoliello and M.Aschner , Toxicology of Lead and Its Damage to Mammalian Organs , in Metal Ions in Life Sciences , 2017 , vol. 17, pp. 501–534 ; see chapter 16 in ref. 6

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