Aryl radical initiators accumulated within layered silicates realize polystyrene with directly and regioselectively bonded aryl-terminal groups
Author:
Affiliation:
1. Department of Chemical System Engineering
2. School of Engineering
3. The University of Tokyo
4. Bunkyo-ku
5. Japan
6. Department of Applied Chemistry
7. Ritsumeikan University
8. Kusatsu
Abstract
A novel aryl radical initiator accumulated within a saponite clay resulted in polystyrenes with regioselectively and directly bonded anthracene, naphthalene, and pyrene terminal groups.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04156D
Reference24 articles.
1. Safe storage temperature of peroxide initiators: prediction of self-accelerated decomposition temperature based on a runaway heuristics
2. A Novel “Stable” Radical Initiator Based on the Oxidation Adducts of Alkyl-9-BBN
3. Controlled/“Living” Radical Polymerization with Dendrimers Containing Stable Radicals
4. Safe storage of radical initiators within a polyaromatic nanocapsule
5. Preparation and characterization of exfoliated polystyrene/clay nanocomposites using a cationic radical initiator-MMT hybrid
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