Zinc-based spinel cathode materials for magnesium rechargeable batteries: toward the reversible spinel–rocksalt transition

Author:

Shimokawa Kohei1234ORCID,Atsumi Taruto56784,Harada Maho56784,Ward Robyn E.910114,Nakayama Masanobu56784ORCID,Kumagai Yu1213144,Oba Fumiyasu91011415,Okamoto Norihiko L.1234ORCID,Kanamura Kiyoshi1617184,Ichitsubo Tetsu1234ORCID

Affiliation:

1. Institute for Materials Research

2. Tohoku University

3. Sendai 980-8577

4. Japan

5. Frontier Research Institute for Materials Science (FRIMS)

6. Department of Materials Science and Engineering

7. Nagoya Institute of Technology

8. Nagoya

9. MaDiS/CMi2

10. National Institute of Materials Science (NIMS)

11. Tsukuba

12. Materials Research Center for Element Strategy

13. Tokyo Institute of Technology

14. Yokohama 226-8503

15. Laboratory for Materials and Structures

16. Department of Applied Chemistry

17. Tokyo Metropolitan University

18. Hachioji

Abstract

Stabilizing spinel structures with Zn preferring a tetrahedral environment significantly improves the reversibility of the spinel–rocksalt transition with Mg insertion/extraction.

Funder

Advanced Low Carbon Technology Research and Development Program

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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