Non-oxidative calcination enhances the methane dry reforming performance of Ni/CeO2−x catalysts under thermal and photo-thermal conditions

Author:

Lorber Kristijan1,Shvalya Vasyl2,Zavašnik Janez2ORCID,Vengust Damjan2,Arčon Iztok32,Huš Matej145,Pavlišič Andraž1,Teržan Janvit1ORCID,Cvelbar Uros2ORCID,Likozar Blaž1ORCID,Djinović Petar13ORCID

Affiliation:

1. National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia

2. Jožef Stefan Institute, Jamova Cesta 39, SI-1000 Ljubljana, Slovenia

3. University of Nova Gorica, Vipavska 13, SI-5000 Nova Gorica, Slovenia

4. Association for Technical Culture (ZOTKS), Zaloška 65, 1000 Ljubljana, Slovenia

5. Institute for the Protection of Cultural Heritage (ZVKDS), Poljanska 40, 1000 Ljubljana, Slovenia

Abstract

Calcination in hydrogen or argon improved nickel dispersion and increased the abundance of oxygen vacancies in ceria nanorods. Visible light both accelerated the methane reforming rate and improved H2 selectivity by retarding the RWGS reaction.

Funder

Javna Agencija za Raziskovalno Dejavnost RS

Publisher

Royal Society of Chemistry (RSC)

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