Lignin-based UV-protective Materials

Author:

Shikinaka K.1,Otsuka Y.2

Affiliation:

1. Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology Nigatake, 4-2-1, Miyagino-ku Sendai 983-8551 Japan kaz.shikinaka@aist.go.jp

2. Forestry and Forest Products Research Institute Matsunosato, 1 Tsukuba 305-8687 Japan

Abstract

Protecting living organisms and organic compounds from ultraviolet (UV) radiation is important due to its harmfulness to them. In this chapter, we describe the usefulness of lignin, a plant aromatic polymer, as a UV absorber (UVA). Here, different procedures like simple mixing, chemical reaction with organic/inorganic molecules, and nanoparticulation of lignin derivatives are introduced for its utilization as a UV-absorber. Especially, the nanoparticulated lignin extracted by simultaneous enzymatic saccharification and comminution of plants gives an excellent UV-protective material by combination with a poly(vinyl alcohol) or clay mineral matrix without dramatically affecting the transparency of the matrix. Lignin-based UV-absorbers never need toxic reagents; i.e., lignin is ideal for application as a UVA of packaging films for organic materials. The UV-absorption nature of lignin not only encourages us to treat plant biomass as a high-value organic material, but also decreases the environmental impact because many current UV-absorbers are obtained from toxic petroleum-based reagents.

Publisher

The Royal Society of Chemistry

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