An easy access to α-aryl substituted γ-ketophosphonates: Lewis acid mediated reactions of 1,3-diketones with α-hydroxyphosphonates and tandem regioselective C

An easy access to α-aryl substituted γ-ketophosphonates: Lewis acid mediated reactions of 1,3-diketones with α-hydroxyphosphonates and tandem regioselective C–C bond cleavage

Published:2014 Issue:36 Volume:12 Page:7140-7149
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Pallikonda Gangaram¹²³⁴,Chakravarty Manab¹²³⁴,Sahoo Manoj K.⁵⁶⁷

Affiliation:

1. Department of Chemistry

2. Birla Institute of Technology and Sciences

3. Pilani Hyderabad Campus

4. Hyderabad 500078, India

5. Catalysis Division

6. CSIR-National Chemical Laboratory

7. Pune 411008, India

Abstract

The α-aryl substituted (±)-γ-ketophosphonates are produced by Lewis acid mediated reactions of α-hydroxyphosphonates with 1,3-diketones.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01091D

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3. Methylenomycin B: new syntheses based on .beta.- and .gamma.-keto phosphonates and .gamma.-keto phosphine oxides

4. Enantioselective synthesis of diisopropyl α-, β-, and γ-hydroxyarylalkylphosphonates from ketophosphonates: A study on the effect of the phosphonyl group

5. Cycloaddition Reactions of Allenylphosphonates and Related Allenes with Dialkyl Acetylenedicarboxylates, 1,3-Diphenylisobenzofuran, and Anthracene

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