Luminescent europium(iii) and terbium(iii) complexes of β-diketonate and substituted terpyridine ligands: synthesis, crystal structures and elucidation of energy transfer pathways

Author:

Abbas Zafar1234,Dasari Srikanth1234,Beltrán-Leiva María J.56789,Cantero-López Plinio56789,Páez-Hernández Dayán56789ORCID,Arratia-Pérez Ramiro56789ORCID,Butcher Ray J.1101112,Patra Ashis K.1234ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur 208016

4. India

5. Relativistic Molecular Physics (ReMoPh) Group

6. Ph.D. Program in Molecular Physical Chemistry

7. Universidad Andrés Bello

8. Santiago 8370146

9. Chile

10. Howard University

11. Washington

12. USA

Abstract

A series of coordinatively saturated LnIII complexes: [Ln(R-TPY)(TTA)3] (1–6) were designed and structurally characterized and plausible energy transfer (ET) pathways determined using a theoretical method.

Funder

Science and Engineering Research Board

University Grants Commission

Ministry of Human Resource Development

Fondo Nacional de Desarrollo Científico y Tecnológico

Comisión Nacional de Investigación Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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