A switch strategy for the synthesis of C4-ethylamine indole and C7-aminoindoline <i>via</i> controllable carbon elimination-Reference-Cited by-同舟云学术

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A switch strategy for the synthesis of C4-ethylamine indole and C7-aminoindoline via controllable carbon elimination

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Bo-Sheng¹^ORCID,Deng Bao-Jie¹,Zhi Yuan-Xin¹,Guo Tian-Jiao¹,Wang Yi-Ming¹,Gou Xue-Ya²,Quan Zheng-Jun¹^ORCID,Wang Xi-Cun¹^ORCID,Liang Yong-Min²^ORCID

Affiliation:

1. Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070, China

2. State Key Laboratory of Applied OrganicChemistry, Lanzhou University, Lanzhou 730000, China

Abstract

This manuscript describes a switchable synthesis of biologically active C4-ethylaminoindole and C7-aminoindoline scaffolds by controlling β-carbon elimination, utilizing aziridine as a C–H ethylamination reagent via C–N bond cleavage.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC05111D

Reference65 articles.

1. Rings in Drugs

2. Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products

3. Development and Application of Indolines in Pharmaceuticals

4. Psilocybin – Summary of knowledge and new perspectives

5. Recreational Use, Analysis and Toxicity of Tryptamines

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