Reversible metal-centered reduction empowers a Ni-Corrin to mimic F430-Reference-Cited by-同舟云学术

Reversible metal-centered reduction empowers a Ni-Corrin to mimic F430

Published:2021 Issue:59 Volume:57 Page:7260-7263
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Brenig Christopher¹²³⁴,Mosberger Leila¹²³⁴,Blacque Olivier¹²³⁴^ORCID,Kissner Reinhard⁵⁶⁴,Zelder Felix¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Zurich

3. CH-8057 Zurich

4. Switzerland

5. Institute of Inorganic Chemistry, ETH Zurich, Vladimir-Prelog-Weg 1-2

6. Zurich

Abstract

This communication presents a novel truncated Ni^II-containing metbalamin and describes its reversible one electron reduction to a catalytically active Ni^I species, that features cofactor F430 model character.

Funder

Universität Zürich

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02945B

Reference33 articles.

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5. B. Kräutler and B.Jaun , in Concepts and Models in Bioinorganic Chemistry , ed. H.-B. Kraatz and N. Metzler-Nolte , Wiley-VCH , Weinheim , 2006

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