Substrate and product role in the Shvo's catalyzed selective hydrogenation of the platform bio-based chemical 5-hydroxymethylfurfural-Reference-Cited by-同舟云学术

Substrate and product role in the Shvo's catalyzed selective hydrogenation of the platform bio-based chemical 5-hydroxymethylfurfural

Published:2014 Issue:26 Volume:43 Page:10224-10234
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Pasini Thomas¹²³⁴⁵,Solinas Gavino¹²,Zanotti Valerio¹²,Albonetti Stefania¹²³⁴⁵,Cavani Fabrizio¹²³⁴⁵,Vaccari Angelo¹²³⁴⁵,Mazzanti Andrea¹²,Ranieri Silvia¹²,Mazzoni Rita¹²

Affiliation:

1. Dipartimento di Chimica Industriale “Toso Montanari”

2. 40136 Bologna, Italy

3. Consorzio INSTM

4. Research Unit of Bologna

5. Firenze, Italy

Abstract

The Shvo's catalyzed selective hydrogenation of HMF to BHMF showed substrate and product effects on the reaction rate. DFT calculation suggested the formation of several intermediates influencing the catalytic cycle.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00304G

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