Synthesis, structural and metal-to-metal charge transfer properties of cyanide-bridged compound [FeII/III-NC-RuII-CN-FeII/III]-Reference-Cited by-同舟云学术

Synthesis, structural and metal-to-metal charge transfer properties of cyanide-bridged compound [Fe^II/III-NC-Ru^II-CN-Fe^II/III]

Published:2022 Issue:8 Volume:46 Page:3978-3984
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wang Yong¹^ORCID

Affiliation:

1. Key Laboratory of Drug Synthesis and Optimization, Jingchu University of Technology, Jingmen, 448000, Hubei, P. R. China

Abstract

Cyanide-bridged mixed-valence complexes trans-[Cp(dppe)Fe(NC)RuII(tbupy)4(CN)Fe(dppe)Cp][PF6]n (n = 2, 3 and 4, respectively, 1–3) were systematically synthesized and characterized in three distinct redox states.

Funder

Hubei Provincial Department of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ05900A

Reference27 articles.

1. The Localized-to-Delocalized Transition in Mixed-Valence Chemistry

2. A Mixed‐Valence {Fe 13 } Cluster Exhibiting Metal‐to‐Metal Charge‐Transfer‐Switched Spin Crossover

3. Pre‐Planarized Triphenylamine‐Based Linear Mixed‐Valence Charge‐Transfer Systems

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