Structure and solvation of confined water and water–ethanol clusters within microporous Brønsted acids and their effects on ethanol dehydration catalysis
Author:
Affiliation:
1. Charles D. Davidson School of Chemical Engineering
2. Purdue University
3. West Lafayette
4. USA
Abstract
Water networks confined within zeolites solvate clustered reactive intermediates and must rearrange to accommodate transition states that differ in size and polarity, with thermodynamic penalties that depend on the shape of the confining environment.
Funder
Ralph W. and Grace M. Showalter Research Trust Fund
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02589E
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