The effect of an electron-withdrawing group in the imidazolium cation: the case of nitro-functionalized imidazolium salts as acidic catalysts for the acetylation of glycerol-Reference-Cited by-同舟云学术

The effect of an electron-withdrawing group in the imidazolium cation: the case of nitro-functionalized imidazolium salts as acidic catalysts for the acetylation of glycerol

Published:2018 Issue:13 Volume:42 Page:10774-10783
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Morais Eduardo M.¹²³^ORCID,Grillo Igor B.⁴⁵⁶³^ORCID,Stassen Hubert K.¹²³^ORCID,Seferin Marcus⁷⁸³^ORCID,Scholten Jackson D.¹²³^ORCID

Affiliation:

1. Instituto de Química

2. UFRGS

3. Brazil

4. Departamento de Química

5. UFPB

6. Cidade Universitária

7. Faculdade de Química

8. PUCRS

Abstract

A simple and inexpensive nitration of the imidazolium cation can considerably increase its acidic activity in the acetylation of glycerol.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ02520G

Reference25 articles.

1. Catalytic role of solid acid catalysts in glycerol acetylation for the production of bio-additives: a review

2. Catalytic conversion of biodiesel derived raw glycerol to value added products

3. SO3H-functionalized ionic liquids as efficient catalysts for the synthesis of bioadditives

4. Heteropolyacid-based ionic liquids as efficient homogeneous catalysts for acetylation of glycerol

5. Synthesis of glycerol triacetate using functionalized ionic liquid as catalyst

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