Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]-Reference-Cited by-同舟云学术

Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]

Published:2016 Issue:22 Volume:45 Page:9127-9135
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Golub I. E.¹²³⁴,Filippov O. A.¹²³⁴,Belkova N. V.¹²³⁴,Epstein L. M.¹²³⁴,Rossin A.⁵⁶⁷⁸,Peruzzini M.⁵⁶⁷⁸,Shubina E. S.¹²³⁴

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds

2. Russian Academy of Sciences (INEOS RAS)

3. 119991 Moscow

4. Russia

5. Istituto di Chimica dei Composti Organometallici

6. Consiglio Nazionale delle Ricerche (ICCOM CNR)

7. 50019 Sesto Fiorentino (Florence)

8. Italy

Abstract

The interaction of alcohols of variable strength with the copper(i) borohydride complex (triphos)Cu(η¹-BH₄) results in a great variety of DHB complexes which encompass different mechanisms involving M–H and E–H bond (E = B, O) activation steps.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01104G

Reference45 articles.

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3. Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules