A coordination cage hosting ultrafine and highly catalytically active gold nanoparticles

Author:

Hang Xinxin1,Wang Shentang2,Pang Huan1ORCID,Xu Qiang134ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Institute for Innovative Materials and Energy, Yangzhou University, Yangzhou 225002, P. R. China

2. School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Soft-Matter Material Chemistry and Function Manufacturing, Southwest University, Chongqing 400715, P. R. China

3. Department of Materials Science and Engineering, SUSTech Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology (SUSTech), Shenzhen 518055, P. R. China

4. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

The size-controlled synthesis of Au NPs was achieved by using a coordination cage CIAC-108 as a support. The Au NPs encapsulated within the cavity of CIAC-108 show smaller size (∼1.3 nm) than the ones (∼4.7 nm) anchored on the surface of CIAC-108.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Chongqing

Natural Science Foundation of Jiangsu Province

Changjiang Scholar Program of Chinese Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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