High temperature ethylene polymerization catalyzed by titanium(iv) complexes with tetradentate aminophenolate ligands in cis-O, N, N chelating mode-Reference-Cited by-同舟云学术

High temperature ethylene polymerization catalyzed by titanium(iv) complexes with tetradentate aminophenolate ligands in cis-O, N, N chelating mode

Published:2014 Issue:33 Volume:43 Page:12663-12677
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Zhao Ruiguo¹²³,Liu Taotao¹²³,Wang Liying¹²³,Ma Haiyan¹²³

Affiliation:

1. Shanghai Key Laboratory of Functional Materials Chemistry and Laboratory of Organometallic Chemistry

2. East China University of Science and Technology

3. Shanghai 200237, P. R. China

Abstract

A series of titanium and zirconium complexes ligated by tetradentate aminophenolate ligands in cis-O, N, N chelating mode were synthesized. Upon activation with MMAO, they exhibit moderate to high catalytic activities for ethylene polymerization at 30–120 °C.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01122H

Reference103 articles.

1. Extrem verzerrte Bindungswinkel bei Organozirconium-Verbindungen, die gegen Ethylen aktiv sind

2. „Lebende Polymere” bei Ziegler-Katalysatoren extremer Produktivität

3. Highly active metallocene catalysts for olefin polymerization

4. Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst

5. Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts

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