High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group-Reference-Cited by-同舟云学术

High-yielding and facile synthesis of organosilicon compounds containing a m-carboranylmethyl group

Published:2015 Issue:93 Volume:5 Page:76079-76082
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Han Xiao-Jie¹²³⁴⁵,Fei Hua-Feng¹²³⁴⁵,Liu Bo-Zheng¹²³⁴⁵,Tan Yong-Xia¹²³⁴⁵,Zhang Xue-Zhong¹²³⁴⁵,Xie Ze-Min¹²³⁴⁵,Zhang Zhi-Jie¹²³⁴⁵

Affiliation:

1. Laboratory of Advanced Polymer Materials

2. Institute of Chemistry

3. Chinese Academy of Sciences

4. 100190 Beijing

5. PR China

Abstract

A method for synthesizing bis(silymethyl)-m-carborane has been developed, the yield was reached up to 88%. The intermediate Si–Br compound could be functionalized, Si–OH, Si-vinyl, Si-ethynyl and Si–H of bissilylmethyl-m-carborane were synthesized.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA13344K

Reference33 articles.

1. Greatly enhanced thermo-oxidative stability of polybenzoxazine thermoset by incorporation of m- carborane

2. o-Carborane-Containing Poly(siloxane-arylacetylene)s With Thermal and Thermo-Oxidative Stabilities

3. Luminescent m-Carborane-Based π-Conjugated Polymer

4. Synthesis, characterization, and thermal properties of poly(siloxane-carborane)s

5. Polythiophenes with vinylene linked ortho, meta and para-carborane sidechains

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