Versatile redox reactivity of triaryl-meso-substituted Ni(ii) porphyrin-Reference-Cited by-同舟云学术

Versatile redox reactivity of triaryl-meso-substituted Ni(ii) porphyrin

Published:2014 Issue:39 Volume:43 Page:14554-14564
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Dimé Abdou K. D.¹²³⁴,Devillers Charles H.¹²³⁴,Cattey Hélène¹²³⁴,Lucas Dominique¹²³⁴

Affiliation:

1. Institut de Chimie Moléculaire de l'Université de Bourgogne

2. Université de Bourgogne

3. CNRS UMR 6302

4. 21078 Dijon Cedex, France

Abstract

The electrochemical oxidation of a Ni(ii) tri-arylporphyrin leads to the 5-Cl and 5-OH-porphyrins, the meso–meso, meso-β and meso-β/meso-β doubly fused dimers depending on the experimental conditions. Among them, the Ni(ii) 5-Cl-porphyrin is isolated in good yield and its formation mechanism is elucidated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00221K

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