Transient self-assembly of metal–organic complexes

Author:

Ayme Jean-François1ORCID,Bruchmann Bernd1,Karmazin Lydia2ORCID,Kyritsakas Nathalie2

Affiliation:

1. BASF SE, Joint Research Network on Advanced Materials and Systems (JONAS), Carl-Bosch Str. 38, 67056 Ludwigshafen, Germany

2. Service de Radiocristallographie, Fédération de chimie Le Bel FR2010, Université de Strasbourg, 1 rue Blaise Pascal, 67008 Strasbourg, France

Abstract

Trichloroacetic acid was used to temporarily rearrange networks of imine-based metal complexes, enabling the expression of complexes unfavourable in the initial state of the networks. Basic design principles were determined for these networks.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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5. J. W.Steed and J. L.Atwood , Supramolecular Chemistry , Wiley , 3rd edn, 2022

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