A charge transfer state induced by strong exciton coupling in a cofacial μ-oxo-bridged porphyrin heterodimer-Reference-Cited by-同舟云学术

A charge transfer state induced by strong exciton coupling in a cofacial μ-oxo-bridged porphyrin heterodimer

Published:2021 Issue:2 Volume:23 Page:960-970
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zarrabi Niloofar¹²³⁴,Bayard Brandon J.¹²³⁴,Seetharaman Sairaman⁵⁶⁷⁴,Holzer Noah¹²³⁴,Karr Paul⁸⁹¹⁰⁴,Ciuti Susanna¹¹¹²¹³¹⁴^ORCID,Barbon Antonio¹¹¹²¹³¹⁴^ORCID,Di Valentin Marilena¹¹¹²¹³¹⁴^ORCID,van der Est Art⁵¹⁵¹⁶¹⁷^ORCID,D’Souza Francis⁵⁶⁷⁴^ORCID,Poddutoori Prashanth K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. University of Minnesota Duluth

3. Duluth

4. USA

5. Department of Chemistry

6. University of North Texas

7. Denton

8. Department of Physical Sciences and Mathematics

9. Wayne State College

10. Wayne

11. Dipartimento di Scienze Chimiche

12. Università degli studi di Padova

13. 35131 Padova

14. Italy

15. Brock University

16. St. Catharines

17. Canada

Abstract

Photodynamics of an aluminum(iii) porphyrin-phosphorous(v) porphyrin heterodimer reveals initial formation of a singlet CT state which relaxes to a high-energy triplet CT state lasting for about 105 μs.

Funder

Natural Sciences and Engineering Research Council of Canada

National Science Foundation

Swenson College of Science and Engineering, University of Minnesota Duluth

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05783E

Reference60 articles.

1. Photosystem II: The Reaction Center of Oxygenic Photosynthesis