Multistep energy and electron transfer processes in novel rotaxane donor–acceptor hybrids generating microsecond-lived charge separated states
Author:
Affiliation:
1. Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials
2. Friedrich-Alexander-Universität Erlangen-Nürnberg
3. D-91058 Erlangen
4. Germany
5. Department of Chemistry
6. New York University
7. New York
8. USA
Abstract
A new set of [Cu(phen)2]+ based rotaxanes, featuring [60]-fullerene as an electron acceptor and a variety of electron donating moieties, namely zinc porphyrin (ZnP), zinc phthalocyanine (ZnPc) and ferrocene (Fc), has been synthesized and fully characterized.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02895G
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