Glassy and liquid Sb2S3: insight into the structure and dynamics of a promising functional material

Author:

Kassem Mohammad1,Benmore Chris J.2,Tverjanovich Andrey3ORCID,Usuki Takeshi4,Khomenko Maxim5,Fontanari Daniele1,Sokolov Anton1ORCID,Ohara Koji6ORCID,Bokova Maria1ORCID,Kohara Shinji7ORCID,Bychkov Eugene1ORCID

Affiliation:

1. Laboratoire de Physico-Chimie de l’Atmosphère, Université du Littoral Côte d’Opale, 59140 Dunkerque, France

2. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA

3. Institute of Chemistry, St. Petersburg State University, 198504 St. Petersburg, Russia

4. Faculty of Science, Yamagata University, Yamagata 990-8560, Japan

5. ILIT RAS-Branch of the FSRC “Crystallography and Photonics” RAS, 140700 Shatura, Moscow Region, Russia

6. Research and Utilization Division, Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan

7. Quantum Beam Field, Research Center for Advanced Measurement and Characterization, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

Abstract

High optical and electric contrast between the SET (crystalline) and RESET (amorphous) logic states is related to the different short and intermediate range order in orthorhombic and vitreous Sb2S3.

Funder

U.S. Department of Energy

Région Hauts-de-France

Ministère de l'Enseignement Supérieur et de la Recherche

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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