Co-electrocatalytic CO2reduction mediated by a dibenzophosphole oxide and a chromium complex

Author:

Koellner Connor A.1,Reid Amelia G.1,Machan Charles W.1ORCID

Affiliation:

1. Department of Chemistry, University of Virginia, McCormick Rd, PO Box 400319, Charlottesville, Virginia 22904-4319, USA

Abstract

A dibenzophosphole oxide is intrinsically inactive for electrocatalytic CO2reduction, however, when combined with a Cr complex it can coordinate in a reduced state, facilitating electron transfer and improving activity.

Funder

U.S. Department of Energy

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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