Application of the stabilization effect of a silyl group in radical-polar crossover reactions enabled by photoredox-neutral catalysis-Reference-Cited by-同舟云学术

Application of the stabilization effect of a silyl group in radical-polar crossover reactions enabled by photoredox-neutral catalysis

Published:2021 Issue:19 Volume:8 Page:5303-5309
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yang Naiyuan¹,Fang Yewen²³^ORCID,Xu Fenfen²,Zhou Rong¹^ORCID,Jin Xiaoping⁴,Zhang Li⁴,Shi Jianxun⁴,Fang Jianghua²,Wu Hao²,Zhang Zongyong²

Affiliation:

1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, No. 79 West Street Yingze, Taiyuan 030024, China

2. School of Materials and Chemical Engineering, Ningbo University of Technology, No. 201 Fenghua Road, Ningbo 315211, China

3. Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, No. 345 Lingling Road, Shanghai 200032, China

4. Department of Pharmaceutical Engineering, Zhejiang Pharmaceutical College, No. 888 Yinxian Avenue East, Ningbo 315100, China

Abstract

Taking advantage of the stabilization effect of a silyl group, with a bulky but positive nature, a range of less investigated organosilanes could be generally accessed via photoredox-catalysed radical-polar crossover reactions.

Funder

Natural Science Foundation of Ningbo

Natural Science Foundation of Zhejiang Province

Science and Technology Innovation 2025 Major Project of Ningbo

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00738F

Reference63 articles.

1. C(sp 2 )−Si Bond Functionalization through Intramolecular Activation by Alkoxides