Preferential population of Al atoms at the T4 site of ZSM-35 for the carbonylation of dimethyl ether-Reference-Cited by-同舟云学术

Preferential population of Al atoms at the T4 site of ZSM-35 for the carbonylation of dimethyl ether

Published:2022 Issue:16 Volume:12 Page:4993-4997
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Xiong Zhiping¹²,Qi Guodong³,Bai Luyi¹,Zhan Ensheng¹^ORCID,Chu Yueying³,Xu Jun³^ORCID,Ta Na¹,Hao Aijing¹²,Deng Feng³^ORCID,Shen Wenjie¹^ORCID

Affiliation:

1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

2. University of Chinese Academy of Sciences, Beijing, China

3. National Centre for Magnetic Resonance in Wuhan, State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, China

Abstract

ZSM-35, synthesized using dioxane as the structure-directing agent, featured preferential population of Al atoms at the T4 site in the 8-MR pore, and the Brønsted acid site, thus generated, catalyzed DME carbonylation actively and stably.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY01112C

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