Synthesis, crystal structures, photophysical, electrochemical studies, DFT and TD-DFT calculations and Hirshfeld analysis of new 2,2′:6′,2′′-terpyridine ligands with pendant 4′-(trimethoxyphenyl) groups and their homoleptic ruthenium complexes-Reference-Cited by-同舟云学术

Synthesis, crystal structures, photophysical, electrochemical studies, DFT and TD-DFT calculations and Hirshfeld analysis of new 2,2′:6′,2′′-terpyridine ligands with pendant 4′-(trimethoxyphenyl) groups and their homoleptic ruthenium complexes

Published:2020 Issue:27 Volume:44 Page:11471-11489
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ramesh Golla¹²³⁴⁵,P. Raghavendra Kumar¹²³⁴⁵^ORCID,Pillegowda Manohar⁶⁷⁸⁹⁵,Periyasamy Ganga⁶⁷⁸⁹⁵^ORCID,Suchetan P. A.¹²³⁴⁵,Butcher R. J.⁶¹⁰¹¹¹²^ORCID,Foro Sabine¹³¹⁴¹⁵¹⁶,Nagaraju G.⁶¹⁷⁴⁵

Affiliation:

1. Department of Studies and Research in Chemistry

2. UCS

3. Tumkur University

4. Tumakuru

5. India

6. Department of Chemistry

7. Jnana Bharathi Campus

8. Bangalore University

9. Bangalore 560 056

10. Howard University

11. Washington DC

12. USA

13. Institute of Materials Science

14. Darmstadt University of Technology

15. Darmstadt

16. Germany

17. Siddaganga Institute of Technology

Abstract

[Ru(L1)₂](PF₆)₂ (1) and [Ru(L2)₂](PF₆)₂ (2): X-ray structures, CH⋯F/O, OH⋯F/N, CH⋯O/π, π⋯π interactions, absorption and emission spectra, DFT/TD-DFT, Hirshfeld analysis.