Synergetic stability enhancement with magnesium and calcium ion substitution for Ni/Mn-based P2-type sodium-ion battery cathodes

Author:

Fu Hongwei1,Wang Yun-Peng2,Fan Guozheng3,Guo Shan1,Xie Xuesong1,Cao Xinxin1ORCID,Lu Bingan4ORCID,Long Mengqiu5ORCID,Zhou Jiang16ORCID,Liang Shuquan1ORCID

Affiliation:

1. School of Materials Science and Engineering, Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province, Central South University, Changsha 410083, China

2. School of Physics and Electronics, Hunan Key Laboratory for Super-micro Structure and Ultrafast Process, Central South University, 932 South Lushan Road, Changsha, China

3. Bremen Center for Computational Materials Science, University of Bremen, Bremen 28359, Germany

4. School of Physics and Electronics, State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha 410082, China

5. School of Physics and Electronics, Central South University, Changsha 410083, Hunan, P. R. China

6. College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hunan 416000, P. R. China

Abstract

A synergetic effect involving Mg and Ca can reduce the adverse impact on redox reactions related to Ni–O bonding in Mg and Ca co-doped P2-Na0.67Ni0.33Mn0.66O2 material, leading to better overall properties than its singly-doped counterparts.

Funder

National Natural Science Foundation of China

Distinguished Young Scholar Foundation of Hunan Province

Central South University

Youth Talent Foundation of Hunan Province of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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