Both end-on and end-to-end azide bridged tetranuclear ferromagnetic nickel(ii) Schiff base complexes

Author:

Bhattacharyya Anik12345,Das Mithun12345,Bauzá Antonio678910,Herrero Santiago1112131415ORCID,González-Prieto Rodrigo1112131415ORCID,Frontera Antonio678910ORCID,Chattopadhyay Shouvik12345ORCID

Affiliation:

1. Department of Chemistry

2. Inorganic Section

3. Jadavpur University

4. Kolkata 700032

5. India

6. Departamento de Química

7. Universitat de les Illes Balears

8. Crta. de Valldemossa km 7.5

9. Palma 07122

10. Spain

11. Departamento de Química Inorgánica

12. Facultad de Ciencias Químicas

13. Universidad Complutense de Madrid

14. Ciudad Universitaria

15. Madrid 28040

Abstract

Variable temperature magnetic measurement of a tetranuclear nickel(ii) complex, consisting of two pseudo-dinuclear entities, indicates the presence of intra- and inter-dinuclear ferromagnetic interactions, corroborated by DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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