Base-catalyzed selective esterification of alcohols with unactivated esters-Reference-Cited by-同舟云学术

Base-catalyzed selective esterification of alcohols with unactivated esters

Published:2018 Issue:44 Volume:16 Page:8467-8471
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Chunyan¹²³⁴⁵^ORCID,Zhang Guoying¹²³⁴⁵^ORCID,Luo Shizhong¹²³⁴⁵,Wang Chunfu¹²³⁴⁵,Li Huiping¹²³⁴⁵

Affiliation:

1. Key Laboratory of Sensor Analysis of Tumor Marker

2. Ministry of Education

3. Shandong Key Laboratory of Biochemical Analysis

4. Key Laboratory of Analytical Chemistry for Life Science in Universities of Shandong

5. College of Chemistry and Molecular Engineering

Abstract

tert-Butyl esters were identified as efficient esterification reagents for base-catalyzed esterification reactions, and mechanistic studies provided evidence of an exchange of the tert-butyl alkoxide metal with alcohol.

Funder

Natural Science Foundation of Shandong Province

Qingdao University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB02411A

Reference80 articles.

1. Transesterification

2. The selective acetylation of primary alcohols in the presence of secondary alcohols in carbohydrates

3. Silphos [PCl3−n(SiO2)n]: a heterogeneous phosphine reagent for formylation and acetylation of alcohols and amines with ethyl formate and acetate

4. Cover Picture: (ChemPlusChem 1/2017)

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