Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study

Author:

Zegke Markus1234ORCID,Zhang Xiaobin5678,Pidchenko Ivan9101112,Hlina Johann A.1234ORCID,Lord Rianne M.1234ORCID,Purkis Jamie1234,Nichol Gary S.1234ORCID,Magnani Nicola1314151612,Schreckenbach Georg5678ORCID,Vitova Tonya9101112ORCID,Love Jason B.1234ORCID,Arnold Polly L.1234ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. The University of Edinburgh

3. Edinburgh EH9 3FJ

4. UK

5. Department of Chemistry

6. University of Manitoba

7. Winnipeg

8. Canada

9. Institute for Nuclear Waste Disposal (INE)

10. Karlsruhe Institute of Technology (KIT)

11. 76021 Karlsruhe

12. Germany

13. Institute for Transuranium Elements

14. Joint Research Centre

15. European Commission

16. 76125 Karlsruhe

Abstract

Uranyl Pacman takes them all: the bonding of s- and d-block cations to uranyl is compared by experiment, spectroscopy and theory.

Funder

H2020 European Research Council

Austrian Science Fund

Engineering and Physical Sciences Research Council

European Cooperation in Science and Technology

Helmholtz-Gemeinschaft

University of Edinburgh

Technische Universität München

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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